Environmental remediation of soils polluted mainly cadmium, zinc, and copper

  • V. L. Samokhvalova National Scientific Centre «O. N. Sokolovsky Institute for Soil Science and Agrochemistry»
  • Y. A. Pogromskaya National Scientific Centre «O. N. Sokolovsky Institute for Soil Science and Agrochemistry»
  • A. I. Fateev National Scientific Centre «O. N. Sokolovsky Institute for Soil Science and Agrochemistry»
  • S. G. Zuza National Scientific Centre «O. N. Sokolovsky Institute for Soil Science and Agrochemistry»
  • V. A. Zuza National Scientific Centre «O. N. Sokolovsky Institute for Soil Science and Agrochemistry»
Keywords: heavy metals (cadmium, zinc, copper), technogenic pollution of soils, the method, remediation

Abstract

The method of remediation of soil technogenic polyelemental contaminated mainly Cd, Zn and Cu, where due to the use as a sorbent - ameliorants compounds of iron (II) and phosphate fertilizers in a certain ratio in accordance with the level of contamination of soils, increase in the efficiency of their environmental rehabilitation and recovery 's natural buffer properties, through influence on the processes of different hazard classes heavy metals migration and trophic regime in the soil, and of the plants productivity with higher rates of ecological safety. The technical result of the elaboration method is to accelerate the processes of heavy metals physical and chemical fixation by making joint structuring improver of inorganic type together with mineral substrates that are effectively reduce toxicity of pollutants, optimization and restoration of the environmental state of the soil-plant system, its resistance to pollution by heavy metals. The elaboration of the method involved the improvement of the known method, accelerated of the of physical-chemical fixation processes of heavy metals different hazard classes by application of soil improver of inorganic type compatible with the type of inorganic mineral substrates, which enables for effective impact on expanding the range of heavy metals different hazard classes unable to migration into adjacent soil environment and on their mobility, to provide optimization and restoration of the soil-plant system ecological state, its resistance to heavy metals pollution. Distinctive features and benefits of the proposed technical solution, compared with known techniques and approaches are the following: ensuring the effective reduction of the heavy metals toxicity of danger various classes with optimal conditions of physical and chemical adsorption mainly Cd, Zn and Cu by simultaneous restoration of natural soil properties (elemental composition, physical and chemical properties for the improvement of organic matter and soil trophic mode) and an allowance of the soil nutrients; resource costs reduce complexity and implementation procedures for environmental rehabilitation of contaminated soils at different levels of heavy metals pollution in areas of impact sustainable sources influence of technogenic emissions due to the accuracy of the determining the ratio of soil improvers inorganic type doses and fertilizers, effective impact of the proposed composition of the first year of application and prolongation of validity up to 5 years.

References

Dovidnyk agronoma po udobrenju, 1962 [Reference agronomist for fertilizing]. Ed. by P. A. Vlasyuk, P. A. Dmitrenko. Dergsilgospvydav, Kiev (in Ukrainian).
Bayrak, M. V., Zuza, V. A., 2001. Sulfaty zaliza – meliorant tekhnogenogo zabrudnenja gruntiv [Iron sulphates – soils meliorant in technogenic pollution]. Vestnik KSAU. A series of Soil science and Agrochemistry. 3, 160–162 (in Ukrainian).
Diagnostika stanu khimichnykh elelmentiv systemy grunt-roslyna, 2012 [Diagnostics of the chemical elements in the soil-plant system]. Ed. by Fateev, A. I., Samokhvalova, V. L. City Printing house, Kharkov (in Ukrainian).
DP na vynakhid 55960 UA, 2003. Sposib znyzhenja vmistu rukhomykh form vazhkykh metaliv u tekhnogeno zabrudnenomu grunti [SE for invention 55960 UA, 2003. Method of reducing the heavy metals mobile forms content in technogenic contaminated soils]. Kramarev, S. M., Nakovski, S. R., Yakovishi-na, T. F. Publ. 15.04.2003, bul. 4 (in Ukrainian).
Fateev, A. I., Samokhvalova, V. L., 2012. Detoxicatsia vazhkykh metaliv u gruntovij systemi [Detoxification of heavy metals in the soil system. Scientific-methodical edition (methodical recommendations)]. Musicdrug, Kharkov (in Ukrainian).
Metodicheskie recomendatcii po gigienicheskomu obosnovaniu PDK khimicheskikh vetsestv v pochve. 1982 [Methodical recommendations on hygienic substantiation of chemical substances MPCs in the soil] (in Russian).
Pat. na korysnu model 20299 UA, 2007. Sposib detoxicatsii vazhkukh metaliv u systemi grunt-roslyna [Pat. for useful model 20299 UA, 2007. Method of heavy metals detoxication in the soil-plant system]. Fateev, A. I., Samokhvalova, V. L.; publ. 15.01.2007, bul. 1 (in Ukrainian).
Pat. na korysnu model Pat. for useful model 85002 UA, 2013. Sposib remediatsii tekhnogeno zabrudnenogo vazhkumu metalamu gruntu [Method of soil remediation technogenic contaminated by heavy metals]. Samokhvalova, V. L., Fateev, A. I., Zuza, S. G., Zuza, V. A.; publ. 11.11.2013, bul. 21 (in Ukrainian).
Pat. na korysnu model Pat. for useful model 85544 UA, 2013. Sposib ecologichnoji reabilitatsiji gruntu tekhnogeno zabrudnenogo perevazhno cadmium, svintsem, tsynkom ta khromom [Method of ecological rehabilitation of technogenic soil contaminated primarily cadmium, lead, zinc and chromium]. Samokhvalova, V. L., Fateev, A. I., Zuza, S. G., Zuza, V. A., Gorakina, V. M.; publ. 25.11.2013, bul. 22 (in Ukrainian).
Pat. na poleznuy model 2210438 RU, 2003. Sposob ochistku i rekultivatsii selskokhozystvenyh zemel [Pat. for useful model 2210438 RU, 2003. Method of cleaning and reclamation of agricultural land]. Chernyakhovsky, D. A.; publ. 20.08.2003, bul. 14 (in Russian).
Pat. na poleznuy model 2406579 RU, 2010. Sostav dlja rekultivatsii zagrjaznenykh pochv [Pat. for useful model 2406579 RU, 2010. The composition for reclamation of contaminated soils]. Ponomarenko, D. V., Perevalov, S. N., Yashchenko, V. G.; publ. 20.12.2010, bul. 35] (in Russian).
Rozrobyty systemy zakhystu silskogospodarskikh roslyn v zalezhnosti vid pokaznykiv zabrudnenja gruntu v umovakh Donbasu, 2005 [To elaborate the system of agricultural plants protection depending on the indicators of soil pollution in Donbass conditions, 2005: a research report 02.05.05. / NSC " IGA named after A. N. Sokolovsky”. Kharkiv. 70 p. № 0104V003682] (in Ukrainian).
Samokhvalova, V. L., 2007. Vykorystanja antydotiv za zabrudnenja systemy grunt-roslyna vazhkhymy metalamy. Povadomlenja 6. Sposib detoksicatsii vazhkykh metaliv [Using of antidotes for heavy metals pollution of the soil-plant system. Message 6. Method of heavy metals detoxication]. Scientific Bulletin of Uzhgorod NU. Series: Biology. 20, 52–59 (in Ukrainian).
Samokhvalova, V. L., 2007. Otdelnye podkhody k phitomelioratsii pochv pri zagrjaznenii tjazhelymi metalami [Separate approaches to phytomelioration of soils heavy
metals contamination // Industrial botany: condition and prospects of development. Mat. int. Conf. "Industrial botany: condition and prospects of development", Donetsk]. Donetsk. 387–391 (in Russian).
Samokhvalova, V. L., Fateev, A. I., Zuza, S. G., Zuza, V. A., 2013. Sposib remediatsii tekhnogeno zabrudnenogo vazhkumu metalamu gruntu [Method of remediation of technogenic soil contaminated by heavy metals]. Agrochemistry and Soil science. 80, 101–110 (in Ukrainian).
Samokhvalova, V. L., Fateev, A. I., Zuza, S. G., Zuza, V. A., Gorakina, V. M., 2014. Sposib ecologichnoji reabilitatsiji gruntu tekhnogeno zabrudnenogo perevazhno cadmium, svintsem, tsynkom ta khromom [Method of ecological rehabilitation of technogenic soil contaminated mainly cadmium, lead, zinc and chromium]. Agrochemistry and Soil science. 81, 51–59 (in Ukrainian).
Samokhvalova, V. L., Sukhova, L. A., 2007. Priminenie antidotov pri zagrjaznenii systemy pochva-rastenie tjazhelymi metalami. Soobchenie 5. Teoreticheskie podkhody, kriterii I perspecktivy razrabotki detoxicantov [Application of antidotes by heavy metals contamination of the soil-plant system. Message 5. Theoretical approaches, criteria and prospects of detoxicants elaboration]. Gruntoznavstvo. 8(3-4), 19–25 (in Russian).
Sokolova T. A., Dronov T. A, Tolpeshta I. I., 2005. Glilistye mineral v pochvakh [Clay minerals in soils. Tula, Grif&] (in Russian).
Sposoby snyzhenja negatyvnoji dii vazhkykh metaliv na kilkist ta jakist vrozhaju silskogospodarskikh kultur, 2004 [The methods to reduce the negative impact of heavy metals on the quantity and quality of crop, 2004: a research report 02.05.04. / NSC "IGA named after A. N. Sokolovsky”. Kharkov, 35 p.
№ 0104V003682] (in Ukrainian).
Vodyanitsky, Yu. N., 2002. Khimija i mineralogia pochvenogo zheleza [Chemistry and Mineralogy of the soil iron / Yu. N. Vodya-nitsky]. Soil Science Institute named after V. V. Do-kuchaev RAAS, Moscow (in Russian).
Vodyanitsky, Yu. N., 2010. Soedinenija zeleza i ikhrol v okhrane pochv [Iron compounds and their role in soil protection / Yu. N. Vodyanitsky]. Soil Science Institute named after V. V. Dokuchaev RAAS, Moscow (in Russian).

Abstract views: 107
PDF Downloads: 97
Published
2014-02-25
How to Cite
Samokhvalova, V., Pogromskaya, Y., Fateev, A., Zuza, S., & Zuza, V. (2014). Environmental remediation of soils polluted mainly cadmium, zinc, and copper. Fundamental and Applied Soil Science, 15(1-2), 42-52. https://doi.org/https://doi.org/10.15421/041404

Most read articles by the same author(s)